云制造平台资源需求的高效匹配策略研究

为快速、精确地从云制造平台资源池中搜索到满足用户需求的资源,实现资源与需求的高效匹配,提出了一种资源需求高效匹配策略。首先,建立了资源与需求的形式化描述模型,在此基础上,采用改进的K-means聚类算法按基本信息进行聚类,对云服务池中的资源进行预处理,形成多个资源簇;其次,计算用户需求与各资源簇聚类中心基本信息的相似度,确立备选资源簇;最后,再分别从资源的状态信息、功能信息和服务信息3个方面对备选资源簇中的备选资源进行筛选匹配。实例分析和研究结果表明:与已有的匹配方法相比,该方法在保持较高匹配精度的同时具有更高的匹配效率。     

Synthesis and analysis of phase segregation of polystyrene-block-poly(methyl methacrylate) copolymer obtained by Steglich esterification from semitelechelic blocks of polystyrene and poly(methyl methacrylate)

Here, an alternative route to successfully synthesize polystyrene-block-poly(methyl methacrylate) (PS-b-PMMA) is reported. Steglich esterification was used as an effective, metal free approach for coupling carboxylic terminated PS and the hydroxyl end-functionalized PMMA chains obtained by nitroxide-mediated polymerization and atom transfer radical polymerization, respectively. α-Functionalization was obtained using 4,4′-azobis(4-cyanovaleric acid) and 2,2,2-tribromoethanol as initiators. The synthesis of PS-b-PMMA was confirmed by gel permeation chromatography and nuclear magnetic resonance (NMR), while the dependence of the diffusion coefficients of the polymers (PS, PMMA, PS/PMMA blend, and PS-b-PMMA) with their corresponding molecular weights was discussed based on the results of atomic force microscopy-based infrared spectroscopy, differential scanning calorimetry, and spectra of diffusion-ordered NMR spectroscopy. Differently from PS-b-PMMA, a partial segregation was observed for the PS/PMMA blend, affecting its thermal behavior and diffusion coefficient. The study here presented provides an easier and efficient strategy for the synthesis of PS-b-PMMA and new insights into the diffusion of polymers.     

Digital Extraction Column: Measurement and Modeling Techniques

The digitization of extraction columns requires a profound knowledge of the present hydrodynamics/mass transport interaction as well as appropriate measurement techniques for the detection of relevant input and target values. In this article, the different techniques for droplet size distribution as well as concentration determination are presented and new methods for online evaluation are discussed. In combination with the simulation of droplet size, holdup and solute concentration distribution, an online-capable process tool for controlling and optimizing extraction columns will be obtained.     

遗传算法和模矢法结合的概率积分法参数反演方法

遗传算法在反演概率积分法预计参数时从参数取值范围内的串集开始搜索,并使用弹性策略来维持群体的多样性,使得算法可以跨过局部收敛的障碍,向全局最优解方向进化;但这种概率化的寻优算法存在局部探索能力差、结果不稳定的缺陷,只能获得问题的近似最优解。模矢法是一种降梯度算法,算法局部探索能力强、收敛快;但这种算法对初值选取敏感,初值选择不当易陷入局部极值。本文提出并实现了一种模矢法与遗传算法结合的组合算法:先使用遗传算法求得参数的全局近似最优解,然后将近似最优解作为探索初值,使用模矢法获得参数的稳定、精确最优解。研究结果表明:组合算法反演概率积分法预计参数的精确度高、收敛快、稳定性好,综合性能较遗传算法和模矢法有明显优势。     

煤炭生产、消费与工业SO2排放关系计量研究——以西部8省为例

研究目的：探究工业SO₂排放与煤炭生产、消费存在必然的联系。研究方法：相关分析方法和改进的物理学重心模型。研究结果表明：(1)时序特征显示:西部煤炭生产、煤炭消费量和工业SO₂排放量整体都呈现上升趋势,三者增长率均呈现多波峰“M”状波动。2)重心轨迹显示:工业SO₂排放轨迹呈现为“倒L”型,煤炭生产和消费轨迹呈现为“J”型。(3)综合对比发现:煤炭生产从源头上影响工业SO₂排放,煤炭消费从空间上影响工业SO₂排放,为消减工业SO₂排放改善生态环境,必须在优先减少煤炭消费增加清洁能源比重的同时,更应该关注对煤炭生产过程的管控。     

Amine-impregnated natural zeolite as filler in mixed matrix membranes for CO2/CH4 separation

Flat mixed matrix membranes (MMMs) comprising polysulfone and clinoptilolite-type natural zeolite were prepared by casting. Zeolite was modified with three alkylamines: ethanolamine (EA), bis(2-hydroxypropyl)amine (BHPA), and polyethylenimine (PEI) by the impregnation method. Impregnated zeolite samples were characterized by X-ray diffraction, Fourier transform infrared spectroscopy, and N₂ adsorption–desorption. The alkylamine loading extent determined by thermogravimetric analysis was 5.2, 4.8, and 8.5% for EA, BHPA, and PEI, respectively. Analyses of MMMs showed that the incorporation of impregnated zeolite affected the glass-transition temperature (T_g) and mixed-gas transport properties. In this regard, a decreasing trend of the T_g values from 185.5 °C for the polymeric membrane up to 176.6 °C for Clino-EA-based MMM was recorded. In addition, the gas separation performance was evaluated at two different feed pressures. At 50 psi, MMMs showed an enhancement up to 30% on the CO₂ permeability (22.79 Barrer) and 55% on the CO₂/CH₄ selectivity (45.78) in comparison with the polymeric membrane (CO₂ permeability 17.34 Barrer; CO₂/CH₄ selectivity 29.38). These values varied depending on the alkylamine, BHPA being the most selective. © 2019 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2020 , 137, 48286.     

The study of short-shot water-assisted injection molding of short glass fiber reinforced polypropylene

water penetration length and fiber orientation (along the melt flow direction) are important indicators for water-assisted injection molding products of the fiber-reinforced polymer. The effects of melt short shot size, water injection delay time and water injection pressure on these two important indexes are analyzed theoretically and experimentally. The study found that with the increase of the melt short shot size, the extension of the water injection delay time and the increase of the water injection pressure, the water penetration length changed from 216 to 96 mm, 170 to 210 mm, and 215 to 180 mm, respectively. Therefore, it can be known that melt short shot size has the greatest influence on water penetration length, followed by water injection delay time, and finally water injection pressure. Meantime, due to the fiber orientation and change degree of water-assisted injection-molded products along the melt flow direction, the fiber orientation in the water channel layer along the melt flow direction has the highest and lowest change degree, followed by the wall layer and finally the core layer. It can be known that the melt short shot size has the greatest influence on the fiber orientation and the degree of change along the melt flow direction, followed by the water injection delay time, and finally the water injection pressure.     

An optimization method to find the thermodynamic limit on enhancement of solar thermal decomposition of methane

An optimization approach to enhancing the solar thermal decomposition of methane (TDM) reaction process based on the fluid flow pattern reconstruction is proposed. The sum of entropy generations due to TDM reaction and heat convection in the process is shown to tend to its maximum when the performance of the reaction is enhanced, and thus, is used as the criterial to optimize the velocity field of the fluid. This optimization problem is solved by the calculus of variations method. The obtained flow pattern is shown to be able to give the conditions to achieve the optimally enhanced TDM process. As the sum of the entropy generations tends to its extremum, the solution found by the optimization can be known as the thermodynamic limit for the TDM process enhancement. The obtained flow pattern can then be used to inspire the design of internal structures of the solar TDM reactor.     

一种使用多维度直方图匹配的图像风格迁移算法

在传统的基于直方图匹配的图像风格迁移算法的基础上，提出一种新的基于多维度直方图匹配的图像风格迁移算法。通过构建关于原图像的不同维度的直方图，然后进行原图像和目标图像的匹配，分别得到原图像在不同维度直方图下的风格迁移图像，最后对这些风格迁移后的图像进行融合生成最终的结果。在保持原图像与目标图像整体风格上尽量相似的情形下，同时又使原图像的局部细节尽可能保留，实现整体风格相似却又保留局部细节的平衡。